First principles computational studies of spontaneous reduction reaction of Eu(III) in eutectic LiCl‐KCl molten salt

Using first principles calculations, we study fundamental mechanism of spontaneous reduction reaction of Eu³⁺ to Eu²⁺ in eutectic LiCl‐KCl molten salt. We decouple the reaction Gibbs free energy into enthalpy and entropy contributions by using rigorous thermodynamic formalism. Key structural features of the solvation shell are characterized by the radial distribution function and the coordination number. Compared with Eu²⁺, the Eu³⁺ ion has a more rigid framework of the solvation shells, corroborating its stronger electrostatic interaction with neighboring ligands of Cl^? ions and a more favorable state on the aspect of enthalpy. Computations on vibrational frequency, however, pose significant contribution of vibrational entropy to the reaction Gibbs free energy for the reduction. Vibration frequency of Eu²⁺ is smaller than that of Eu³⁺, driving a more positive change of the entropy in the reduction reaction. Furthermore, an Eu²⁺ diffuses more quickly than an Eu³⁺ in the LiCl‐KCl molten salt with switching mechanism of ligand Cl^? ions in the solvation shell. Our results propose that the spontaneity of the reduction reaction is driven by the entropic contribution by overcoming the penalty of the reaction enthalpy.     

Beta-Binomial删除信道中的喷泉码文件传输协议

由于命名数据网络(NDN,Named-Data Networking)无环路、逐包、逐跳转发的特点,使得数据包回传成功率降低,而传统的TCP/IP协议中的ARQ和ACK机制对于多播会话不再适用.由于NDN中的传输信道可以等效为二进制删除信道,因此可以通过应用层编码来实现文件的可靠传输.传统的信道编码技术如卷积码、级联码和RS码等复杂度较高,而将NDN与低复杂度的喷泉码的结合可以实现分布式的存储架构,因而可通过喷泉编码在应用层协议中实现可靠的纠删机制,保证整体文件的传输可靠性.以往的研究一般是基于确定的删除概率信道模型,但是由于网络的异构性和信道噪声等因素影响,可能会造成信道丢包概率呈随机性分布.因此,本文在Beta-Binomial分布模型的前提下,根据贝叶斯统计的先验信息和中心极限定理,对随机概率下的纠删信道的文件可靠传输协议进行了数学建模和理论推导.仿真结果显示此模型更具有普适性,此传输协议可在信道状况未知的前提下从理论上求出最小发包数,减少冗余编码包,提高文件整体的投递成功率,在保证传输可靠性的同时有效提升协议传输效率.     

A Voltage Control Method for a Distributed Line Feeder by means of Multiagent Approach

This paper proposes a method for the coordinated control of power factor by means of a multiagent approach. The proposed multiagent system consists of two types of agent: single feeder agent (F_AG) and bus agent (B_AG). In the proposed system, an F_AG plays as an important role, which decides the power factors of all distributed generators by executing the load flow calculations repeatedly. The voltage control strategies are implemented as the class definition of Java into the system. In order to verify the performance of the proposed method, it has been applied to a typical distribution model system. The simulation results show that the system is able to control very violent fluctuation of the demands and the photovoltaic (PV) generations.     

攀西钒钛磁铁矿尾矿制备储水泡沫陶瓷的研究

以攀西钒钛磁铁尾矿和废玻璃为主要原料通过高温烧结法制备储水泡沫陶瓷，研究原料配比和发泡剂（SiC）添加量对材料性能的影响。结果表明:随着钒钛磁铁矿尾矿含量的增加，材料的体积密度及抗压强度逐渐增大，平均气孔孔径逐渐减小；当尾矿添加量为50 wt%，材料的体积吸水率出现极值。当SiC添加量为0.3 wt%，材料内部气孔分布均匀，平均孔径约为2.93 mm。最终以50.0 wt%的钒钛磁铁矿尾矿和50.0 wt%的废玻璃为原料，外加3.0 wt%的石英，0.3 wt%的SiC，3.0 wt%的Na3PO4，在1040℃下制得性能最优的储水泡沫陶瓷，材料的体积密度为0.26 g/cm-3、体积吸水率为56.5%和抗压强度为0.68 MPa。采用SEM、XRD等检测手段研究材料的微观形貌及物相组成，结果表明储水泡沫陶瓷内部由三维立体结构组成，有利于储存水分；材料主要物相包括硅灰石、长石、透辉石和钛铁矿。      

多晶硅生产中残液搅拌罐密封结构的改造

在处理多晶硅生产中产生的残液时,残液搅拌罐填料密封出现泄漏,针对此问题提出了优化措施,达到了预期效果。     

因素空间理论下基点分类算法研究

目前，基于因素空间理论的背景基提取算法计算过程复杂，初始化必须依赖各因素极值，基点数量提取冗余等原因，未能在应用中取得很好效果。为此，结合内点判别法和知识可继承、可扩展的思想，提出一种计算简单、初始化独立、基点数量小的改进的背景基提取算法。然后，利用改进的背景基提取算法构造出一种全新的数据分类算法-基点分类算法，基点分类算法以提取每一类样本的背景基为预测模型，再通过新定义的λ-背景基，优化预测模型。数值实验表明:基点分类算法原理简单、构造难度小、分类模型泛化能力强，预测能力准确率高，同时严格的模型限定区域又能为识别新类别提供新方法。     

采煤工作面煤层注水参数试验研究

通过在6198采煤工作面现场施工煤层注水钻孔采取煤样,实验室试验注水钻孔水压力分布、煤样含水率变化,得到了工作面煤层注水影响半径等技术参数,为采煤工作面煤层注水提供了一定的参考依据。     

动态结冰孔隙结构三维建模方法

动态结冰内部呈现多孔结构特点，这一微观孔隙结构是影响其宏观物性的关键因素，然而传统方法难以对三维孔隙结构进行定量表征。为了客观刻画结冰微观结构特征，提出了基于结冰二维图像定量信息的三维微观结构建模方法。首先，研究并确定了真实结冰尺寸与建模区域之间的比例关系，分析比例尺对分辨率和建模的影响；其次，结合二维孔隙率和孔径分布函数，提出了三维孔隙数量及其孔径的推导方法，并给定了孔隙位置随机生成方法；基于此，最终建立了以0-1矩阵形式表征结冰三维微观孔隙结构的方法。实验表明，所生成三维结冰模型的二维孔隙定量信息与实验结果吻合度较高，建模方法准确可行，为动态结冰三维刻画、微观特征参数提取和相关微观仿真模拟提供了新途径。     

Additional high-energy milling to enhance the performance of porcelain stoneware manufacturing

Porcelain stoneware tile is the best class of ceramic tiles regarding technical performance. Low porosity and high glass content are some of its highlighted characteristics. The manufacturing cost is highly dependent on the feldspar content and the processing flow rate. Certain technical bottlenecks in the manufacturing steps, such as milling, forming, and firing, are intrinsically associated with limitations in the processing properties, such as the dry strength, bulk density, and pyroplastic deformation. In this work, improvements in these properties were achieved using high-energy milling (HEM) after conventional milling (CM). This study was carried out on a pilot industrial scale in the milling stage. Six experimental runs were evaluated. Slurries were spray-dried. The powders were humidified with 6.5% moisture. Specimens were conformed under a specific pressure of 45 MPa. The firing was performed using temperature ranging from 1150 to 1230°C. The use of HEM, in comparison to traditional milling for the similar particle-size distributions, has increased the dry density, +0.2 g.cm⁻³, dry bending strength, +1.0 MPa, and decreased the pyroplastic deformation index, −1.10⁻⁵ cm⁻¹. These results allow an estimated thickness reduction of 10%.     

自适应SA-PSO优化的威布尔混合分布参数估计方法及应用

针对采用传统参数估计方法得到的模型拟合误差较大的问题，建立多重威布尔混合分布参数估计的非线性最小二乘模型，并提出基于模拟退火（SA）思想的自适应粒子群（PSO）算法进行求解。在PSO算法优化过程中，采用自适应方法调整惯性权重和加速因子，加快其收敛速度；引入模拟退火机制，根据Metropolis准则确定最优粒子的取舍，改善其全局搜索能力。将该方法应用到某型柴油机喷油器失效分布的参数估计中，并与图解法、基于Levenberg-Marquardt的非线性最小二乘法、标准PSO算法、自适应PSO算法求解的结果进行比较，分析所提方法的优化性能及精度。结果表明，该方法能够有效提高多重威布尔混合分布模型参数估计的精度和效率。